Catalytic oxidation of CO on mesoporous codoped ceria catalysts:Insights into correlation of physicochemical property and catalytic activity

Codoping approach is an appealing strategy to further improve the catalytic activity of Ce-based catalysts. In the present study,Mn and/or Cu doped ceria solid solutions MnxCuyCe_(1-x-y)O_2,Cu_xCe_(1-x)O_2,Mn_xCe_(1-x)O_2 and pure CeO_2 were prepared by CTAB-assisted hydrothermal method for CO oxidation.XRD, SEM, EDS, BET, Raman, H2-TPR, XPS and in situ DRIFTS techniques were carried out to study the physicochemical properties and to correlate them to the activity. The doped samples maintain the cubic fluorite structure of CeO_2 with high crystallinity and small crystallite size, forming Ce-based solid solutions. The obtained catalysts have large mesoporous structure with average pore size of 10-14 nm. The doped transition metal enhances the oxygen vacancies and improves reducibility of the solids. The synergistic interaction of Mn and Cu codoping induces mo re oxygen vacancies, pro moting the increase of surface adsorbed oxygen and the transfer of bulk oxygen of catalyst, thereby enhancing the catalytic activity for CO oxidation. Besides, the decomposition rate of the carbonate species which is derived from in situ DRIFTS for each catalyst can provide a measure to evaluate its catalytic activity of CO oxidation.     

歧口凹陷歧北次凹沙河街组三段页岩油地质特征与勘探突破

歧口凹陷歧北次凹沙河街组三段（沙三段）湖泛期细粒沉积发育、烃源岩品质好、页岩油资源丰富，但其研究尚处于起步阶段，在沧东凹陷孔店组二段湖相页岩油工业化开发的带动下，落实其勘探前景势成必然。为探究歧北次凹沙三段页岩油的地质特征及勘探潜力，依据F39X1井、QY10-1-1井等多口井的岩心、分析化验、测井资料和录井资料，对沙三段页岩层系的地质特征、页岩油类型与富集模式、甜点的空间分布规律等开展了综合研究。歧北次凹沙三段的矿物组成和岩石类型多样，主要包括灰质白云质页岩、长英质页岩、混合质页岩及微晶白云岩、亮晶生屑白云岩、粉砂岩等；烃源岩的总有机碳（TOC）含量主要分布在1%~3%，以Ⅱ型干酪根为主且指示热演化成熟度的镜质体反射率（R_o）普遍高于0.7%；储集空间主要包括粒间孔、晶间孔、生物体腔孔、有机孔及层理缝、构造（微）缝等；页岩油的超越效应明显（油饱和度指数平均为116.3 mg/g）、荧光显示良好。在歧北次凹沙三段中识别出单一型和夹层型2类页岩油，构建了高TOC滞留型页岩油和低TOC运移型页岩油2种富集模式，并建立了基于油饱和度指数、TOC和脆性指数等多参数的甜点定量评价方法及标准。针对甜点区部署了QY10-1-1水平井，其初期的折算产油量达103.5 t/d，预计可形成亿吨级增储新领域。勘探发现证实歧口凹陷的沙三段细粒岩段具备良好的页岩油勘探潜力。     

积分中值屈服准则解析厚板轧制椭圆速度场

为解决非线性Mises比塑性功率积分困难以及由此导致的轧制功率解析式难以获得的问题,本文通过建立并利用线性比塑性功率表达式对提出的椭圆速度场进行能量分析,得到了轧制力能参数的解析解.文中通过对变角度屈服函数求积分中值,构建了一个新的屈服准则,它是主应力分量的线性组合,在π平面上的轨迹是逼近Mises圆的等边非等角的十二边形,其基于Lode参数表达式的理论结果也与实验数据吻合较好.同时,根据厚板轧制时金属流动速度从入口到出口逐渐增大的特点,提出了水平速度分量满足椭圆方程的速度场,该速度场满足运动许可条件.通过相应的轧制能量分析,获得了基于线性屈服准则的内部变形功率以及基于应变矢量内积法上的摩擦功率与剪切功率.在此之上,通过泛函的极值变分导出了轧制力矩、轧制力以及应力状态系数的解析解,并与现场实测数据进行了对比,结果表明利用本文提出的屈服准则与速度场所建立的轧制力矩与轧制力模型与实测值吻合较好,其中轧制力误差小于5.3%,轧制力矩误差在6%左右.     

镀液温度实时控制系统的设计与实现

针对镀液温度变化的非线性和滞后性,设计了采用专家规则的镀液温度实时控制系统。该系统在实时监测的基础上,构建了综合评判镀液温度偏差和镀液温度偏差变化率的专家规则,实现了镀液温度的自适应快速调节。仿真分析结果表明,该系统克服了非线性和滞后性的不良影响,能够实现镀液温度的实时控制。     

抽油机变速运行智能控制技术深化研究与应用

探究了抽油机合理的下冲程时间比,建立了多控制目标与自寻优相结合的抽油机井变速运行智能控制模型;应用功率峰值平衡度与功率均值平衡度,提出了判断抽油机井平衡度的新方法,解决了峰值电流法因反向发电而无法准确判断抽油机井平衡度的问题,实现了抽油机井平衡度的实时监测与调整;设计了前端控制与后台云端分析相结合的变速运行控制方案,弥补了抽油机变速运行智能控制技术井况适应区间狭窄,控制策略可变参数单一的局限性,拓展了井况适用范围,取得了良好的节电、增油效果。     

On a class of mixed EWMA-CUSUM median control charts for process monitoring

Monitoring of any manufacturing, production, or industrial process can be controlled and improved by removing these special cause of variations using control charts. Shewhart-type control charts are effective to control a large amount of special variations, whereas, cumulative sum (CUSUM) and exponentially weighted moving average (EWMA) charts detect small and moderate variations efficiently in the process parameters. Monitoring of location parameter can be done with mean control charts under the assumption that the parameters are known or correctly estimated from in-control samples and data are free from outliers (but in practice data occasionally have outliers). In this study, we have proposed generalized mixed EWMA-CUSUM median control charts structures for known and unknown parameters based on auxiliary variables for detecting shifts in process location parameter. The proposed charts are compared with the corresponding charts for the mean, based on contaminated and uncontaminated data. Different performance measures are used to evaluate the performance of proposed control charts and revealed through results that the median-based charts are more sensitive to detect a shift in process location parameter in the presence of outliers. An illustrative example using real data is also shown for practical consideration.     

读懂衡器的最大允许误差

本文主要讨论衡器的检定分度数能否大于传感器的最大检定分度数nmax,这是一直困扰大家和争论不休的问题。作者由分析最大允许误差mpe本质入手,指出mpe是人为规定的误差,不是传感器实际的物理特性。通过理论分析得出的对单只传感器的衡器,n≤nmax和v≥vmin的误差限原则是不能违背的。对于四只传感器的衡器,不受上述误差限原则限制。     

Modeling of quantitative relationships between physicochemical properties of active pharmaceutical ingredients and tensile strength of tablets using a boosted tree

Objectives: The aim of this study was to explore the potential of boosted tree (BT) to develop a correlation model between active pharmaceutical ingredient (API) characteristics and a tensile strength (TS) of tablets as critical quality attributes.

Methods: First, we evaluated 81 kinds of API characteristics, such as particle size distribution, bulk density, tapped density, Hausner ratio, moisture content, elastic recovery, molecular weight, and partition coefficient. Next, we prepared tablets containing 50% API, 49% microcrystalline cellulose, and 1% magnesium stearate using direct compression at 6, 8, and 10?kN, and measured TS. Then, we applied BT to our dataset to develop a correlation model. Finally, the constructed BT model was validated using k-fold cross-validation.

Results: Results showed that the BT model achieved high-performance statistics, whereas multiple regression analysis resulted in poor estimations. Sensitivity analysis of the BT model revealed that diameter of powder particles at the 10th percentile of the cumulative percentage size distribution was the most crucial factor for TS. In addition, the influences of moisture content, partition coefficients, and modal diameter were appreciably meaningful factors.

Conclusions: This study demonstrates that BT model could provide comprehensive understanding of the latent structure underlying APIs and TS of tablets.     

从战后重建到预防性保护 —— 比利时建筑遗产保护之路

本文分为两个部分,第一部分简述了比利时在不同时期的建筑遗产保护实践,主要包括:第二次世界大战后的战后重建,威尼斯宣言颁布前后的相关实践,1975年"欧洲建筑遗产年"后对"历史文物古迹"的保护延伸到对次要建筑群及其所处环境以及历史城市、村镇的整体性保护,1988年文化遗产保护管理从比利时联邦下放到弗兰芒、瓦隆、布鲁塞尔三区实行分区管理等方面;第二部分着重介绍了比利时在建筑遗产的预防性保护这块的实践,以"文物古迹监护"机构近30年的实践为例,并试图从历史、社会、经济、管理、教育等角度对预防性保护得以成功实施的原因进行了分析。     

基于二元水循环的水量-水质-水效联合调控模型开发与应用

为将我国最严格水资源管理制度的实践与二元水循环理论相结合，提高“三条红线”控制指标的科学性与合理性，本文以SWAT模型为基础，通过改进子流域划分方法、添加经济社会模块和人工用水模块，对其人工侧支循环模拟进行了系统的完善，开发了基于SWAT的水量-水质-水效联合调控模型SWAT_WAQER。以广西南流江流域为例，从国民经济用水量、河道径流与水质等方面对模型进行校验，并在此基础上划分了2030年“三条红线”控制指标。结果表明：该模型性能良好，能够用于不同节水情景下的国民经济用水量、污染物排放量、水功能区水质达标结果分析，可以作为科学制定“三条红线”控制指标的有力支撑工具。